Effect of NAPL mixture and alteration on 222Rn partitioning coefficients: Implications for NAPL subsurface contamination quantification

نویسندگان

چکیده

Soils and groundwater are often contaminated by complex organic mixtures also called Non Aqueous Phase Liquids (NAPLs). Several techniques such as drilling, monitoring of soil gas or injection tracers traditionally used to quantify NAPLs in aquifers but perform. The use natural 222Rn could be an easy cheap alternative. This method requires the knowledge radon NAPL-water partitioning coefficients (Kn-w.). Once spilled on soil, NAPL will undergo degradation (evaporation, effects sun light among others) this impact Kn-w. study aims at investigating commercial diesel fuel gasoline relation evaporation UV-degradation. For that purpose, batch experiments GCMS investigations were carried out. results show different Kn-w for (60.7 ± 6.1) (37.4 5.6). behaviors with degradation. Degraded display opposite values (74.8 7.5 25.1 2.5 UV degraded evaporated fuel, respectively), compared fresh one. shows no significant variations molecular investigation reveals removal most volatile fraction treatment, whereas UV-degradation do not have pronounced chromatogram pattern. investigation, difference is observed between treatments excepted a very slight lightest compounds under evaporation. These gasoline, least these paths. variation fine activity interpretation subsurface quantification.

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ژورنال

عنوان ژورنال: Science of The Total Environment

سال: 2021

ISSN: ['0048-9697', '1879-1026']

DOI: https://doi.org/10.1016/j.scitotenv.2021.148210